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Thank you all for your knowledge and help. Oxidisation it is. They were originally in two other demijohns, before siphoning to leave behind some sediment, but only a little fuller than shown. So I'm lucky to have only one bad one! Having just read up a bit more, I think next year I need to to...

Hello, I'm a complete newby to home brewing, but had a glut of white grapes on a Vine this year so thought I'd give it a go. The picture above is the result. These two both came from the same bucket, done at the same time, and using all the same equipment and additives. They were also both...