During fermentation, you can take a juice sample and de-gas it as much as you can to get a reasonably accurate pH reading. In the future though, get your pH and TA readings at the juice stage. If you need to adjust acid content, this is the best time to do so as it integrates more seamlessly then adding post ferment. Try to avoid de-acidifying if possible, it's just another addition and wine movement that will impact aromatics and flavor.
For your particular situation, wait until ferment has finished and take a pH and TA reading and carefully assess the palate for balance. Remember, you still have the option of Malolactic Fermentation which will lower acidity and round off the palate somewhat. Additionally, you can add grape juice concentrate to balance the acid. Without tasting it, I would set up 100ml trials with say 0.25 grams/litre increments of GJC up to about 2.5 grams per liter. If you can avoid deacidification I definitely would given your current experience level.