Probably not relevant to this plant problem, but 2, 4-D is a broadleaf weed killer. It doesn't kill everything. That's why you can spray it on your lawn and it kills the dandelions and plantain, etc, but not the grass. It can also be sprayed on wheat (wheat is a grass) to kill broadleaf weeds. Grapes, being broadleaf plants are affected by it and are very sensitive to it.