After testing the old came in at 48 ppm and the new 46 ppm. Now I only did one test each so it's not good lab protocol and there is a slight margin for error but I think it is close enough to see that the old is still good.
When at University, one of my Chemistry professors said that he worked his was through college doing titrations. And he said he only took one measurement. Because if he took two, the second one would always be different, so he would then need to take a third one to prove the first one was accurate.
His tongue in check comment was to point out measurement and statistical error.
But also to show that if one knows what they are doing, then any measurement, when properly done, will fall within the standard deviation error of such measurements. So should be okay. A beginner needs to take that third measurement, but an expert may need not.
But, it also I think this data confirms why it is recommended to always retest your wine a day or two after adding KMeta, because of this or other factors may affect the results, and they may not be where you think it should be by the "simple" expectations of "formulas" after a day or two. That is, the world is complicated, and things you read from an external source are ideals, but need not match your personal real world realities, and one should not expect them to. The more experience you gain, the less you need to test repeatedly. Hope this helps.