My batches are about 60L (I use 50 - 55L barrels). I wait until all my wines are ready for MLF, hydrate and divide the hydrated mixture. It's far easier than trying to parcel out small parts of a gram. Because of the short shelf life after opening and because my season is over for a year, I don't try to keep my ML bacteria. (Morewine supplies both Acti-ML and Opti-malo in sizes that match the addition requirements of the bacteria package.)
My answer: without a good scale, and even then, it's difficult to measure out a 10 gallon addition from a 1.5g satchet meant for 66 gallons. I do not think there is a penalty to adding too much ML bacteria; although, I would do what I could to get it close.
FWIW: I understand the small (1.5 - 2.5 gram) ML bacteria packages most home winemakers use are sized to add directly to a 225L barrel. I have witnessed this occur in a large commercial winery. It was crazy to see the cellar personnel climbing amount the barrels making the addition.