John, how are you applying sulfite during barrel aging? I've been adding a full teaspoon at barrel fill (6 gallon) and thinking that would be fine for six months. Sounds like that's a failed thought.
Best bet is to measure and adjust and top up monthly to maintain proper levels, that is how I handle wines in barrels. What I have found, generally speaking, is that my 6 gallon barrels needed 1/8 tsp per month to maintain levels. The 30 and 60 are in the same vicinity, half of the 1/4 tsp per 6 gallons applied monthly.