Hi Benaway,
I'm no expert, all I can offer is my own take...
I think there are a couple of issues here. First, when is the best time to add acid? I adjust preferment, but if anything I'll slightly undershoot at this point, then make postferment adjustments based on taste. By the way, recipes are very rough guides on this; I never blindly add the recommended amount of acid, but rather add according to pH, TA, or both, depending on the wine I'm making.
The second issue is which type of acid to add. There are different types of acid blend and they vary widely in their makeup. For example, I have traditionally used malic/tartaric/citric in
50/10/40 ratio, but they make 40/40/20, and
here is one with 25/25/50. I usually make non-grape wines, and I have found that most of these wines do not benefit from malic acid (apple being the exception of course). So I no longer generally use acid blend...what I now do is use tartaric and/or citric, depending on the wine. Some are mostly tartaric, some are mostly citric.
Robert