I suppose an option is to add sugar just before consuming the wine. Otherwise, your suggestion of making a fortified wine is a fine one.
Another option, albeit expensive, is to invest in ultrafiltration equipment. If you can reliably filter down to a fraction of a micron, you can filter out any remaining yeast. (Google "sterile filtration.")
Essentially it is possible to make wine without most or all common chemicals we use BUT as Sour_Grapes states part of that would require the use of an expensive filtration system normally used only at commercial wineries and by those with deep pockets (Both Equipment and Supplies costs)
Chances are if your wife has had any commercial wine, she has already consumed the typical chemicals used in home wine making.
Chemical Free Wine - This is not a new topic - it has come up multiple times in the 2 1/2 years I've been a member on this forum. The end result of discussions doesn't change. Wine made without basic wine preservation and stabilization chemicals typically doesn't taste as good and even with the use of ultrafiltration equipment the 'natural wines' spoil much faster. Alcohol alone cannot completely protect wines from spoilage.
Then there is also the problem of a wine batch that develops issues during fermentation or aging. The chemicals used there may well run smack into your wife's no chemicals ban.
Not trying to discourage you but the reality it that even commercial wineries have to deal with the occasional batch that develops some off characteristics. They may treat their wine or dump it but for us in the home wine making hobby, dumping is a last resort - there are ways to save most batches but they frequently require the use of some chemicals. Commercial "Natural Wines" (No chemicals used) can be found but most folks who have had them report them to be much less enjoyable wines. Couple of reasons for this is the lack of any added sugars to back-sweeten them and the fact that since they spoil faster, aging them to a point where the flavor improves cannot not be done - the wine spoils before it ages sufficiently.
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