Calcium carb is always the choice when raising PH pre-ferment. Calcium carb in a fruit wine works by neutalizing the acid, since there is no tartrate to convert to calcium tartrate.
Potassium is always used post ferment for tweaking. I know some white papers talk about using it in the must, but many times you're moving the PH many tenths and too much of it CAN damage the nose and flavor of some wines. Potassium carb always needs to be cold stabilized.
However, he already has an acidic wine and when you take an acidic wine into CS, the PH actually FALLS. A wine going into CS at a PH of 3.65 should stay at that PH. PH rises and falls depending on how far away from 3.65 it starts.
This isn't an exact formula due to buffer capacity and ability to get accurate readings. But in general, wines below 3.65 will fall and wines above 3.65 will rise in PH with CS.
So he is better off using calcium carbonate to neutralize the acid, instead of trying to drop it out.
You can also ferment this with 71B culture which will metabolize some of the malic, making the wine less harsh. If you use this culture, be sure to rehydrate it with Go-Ferm.