So you're of the opinion that when you're vacuum degassing keep at it even though you're pulling up the bigger bubbles not anymore small ones?
Thanx...
I think we're missing the point. A can of soda or beer, once opened, degases itself completely without heat or vacuum. To degas your wine, you don't need to pull a high vacuum for a long time. Once you see the foamy little bubbles dissipate, the CO2 is gone.
In fact, if you aren't in a hurry, the wine will naturally degas itself just fine as it bulk ages.
On this, I agree with Jim: degas until you reach the desired level of degassing. I am not 100% sure, but it probably does not require you to continue pumping on it in the "big bubble stage."
My setup allows me to monitor the amount of gas coming out. As I have mentioned before, I use a half-filled carboy and agitate it to speed the gas evolution. Since I am agitating, it is a little hard for me to know when I am in the "big bubble" stage, but this much is true: after 20 minutes or so, the actual amount of gas coming out is very small, even when bubbles are still being produced. (There is not much gas in the bubbles due to the PV=NRT relation referenced above.) Even though there is not much of it, I also taste the gas to get an idea of what it is. Believe me, it is CO2!