Julie
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I use Star San to sanitize. Star san doesn't remove the grape aroma and ring around the carboy no matter how much I scrub.
The aroma should go away fairly quickly as long as you are not sealing the carboy. Use oxyclean if the carboy is getting that stained but stay away from the bleach, especially if you are using the carboys to make beer as well. Bleach will hamper head retention on the beers.