Okay @winemaker81 and @Rice_Guy any other experiments I should do with an open wine? I'm serious! Always willing to learn!
I haven’t done bench trials on either of these to optimize number of drops dosage so I will be interested in what you like, (the vinters club is looking at a judge training program);
volatile acidity, VA; add a drop of 100 grain vinegar to 750 of wine. Mix using a tasting cork. Pour a wine glass and swirl then smell, , , you are looking for a weak salad dressing like odor. Taste wise the odor threshold sample should still be fresh/ acidic and pleasing, it will take another drop(s) to get to where taste starts getting bad. Natural production could be by making kombucha and then use the same carboy on wine.
ethyl acetate, nail polish; take the VA taste sample from above and oxidize it in a milk bottle like a sherry taste sample. Taste every month for six months. , , , I have taken ethyl acetate to vinters meetings and had someone say “This sure doesn’t taste/ smell like NN fruit in contest it wouldn’t place but its pretty good so l’ll have another glass.”
TCA/ Geranium (and all the above); there are flavor standards manufactured in England/ $500ish, where you dose a capsule of chemical into a 750 ml white wine to produce the defect. TCA is nasty since it is sensed at parts per trillion and could kill my taste buds for an hour.