It mighty important to adjust highly acidic fruit, like blackberries, pre-ferment when you can use calcium carbonate. If you don't adjust it pre-ferment, you'll never be able to get it adjusted post-ferment because it's too far out of line. And you can't use alot of potassium carbonate to adjust it in the post ferment environment because potassium carbonate is only for tweaking the acid. You'll be stuck with a highly acidic blackberry that the only thing you can do with it is to blend it.
Get used to taking PH readings on everything before you start your ferments--you'll make much better wines, and avoid the headaches of having an imbalanced wine in the post ferment that you may not be able to adjust. Pre-ferment adjustments always yield a better result anyway. Even when we use Alexander's concentrate---we take PH readings.
To not know what your PH is is to just let the wine do what it wants---winemaking is all about MAKING it happen in the direction you choose. Your work at the primary is where you are designing your wine. This is where all the work should happen--not struggling post ferment.