Don't get too fancy your first year. It's easy to overthink a lot of this. The grapes want to be wine, so it's pretty easy to get the basics right. I #might# recommend just to do a larger amount of one varietal, as opposed to 2 varietals and sort out your processes. It will be easier to keep things topped off and you won't need to worry about whether you mixed things or not.
I do recommend you get a few more carboys of different sizes. It sounds like you have a 14 gallon demijon, and a 5 gallon carboy. I'd get a couple of 3 gallon carboys and three 1 gallon jugs (Carlo Rossi jugs are 4L and widely available). The wine that comes in them can be drunk on a Tuesday night-
. You really want some flexibility in case you end up with say 22L of wine for your 23 L carboy. THen you will have far too much head space and your wine will be at risk for oxidation and vinegar formation.
Heating the must is a very bad idea. Other than the pectin problem, it accelerates oxidation and will harm your flavors-think Jam vs fresh grapes. Your yeast will have no problems with table sugar, you don't even need to dissolve it. The process of punching down the cap will mix it more than enough and the yeast will also assist. But with that said, you likely will not need to add any sugar. Yeasts do differ in their ability to metabolize fructose and glucose but for common commercial yeasts this is a non-issue and they can handle sucrose just fine.
Acid additions are a very good idea if your pH is not where you want it. Use only Tartaric acid (not acid blend), and be careful that it is from natural sources. Synthetic tartaric will have half the molecules in the wrong configuration whereas natural tartaric will all be in the correct L-(+) format you want. Generally if you buy it from a wine supply place it will be correct.
Don't wash the grapes. No need. The bugs and spiders add terrior. Do remove any leaves and most of the stems.
Enzymes are generally an excellent idea. You will get much better color extraction and maybe some flavor too. I use Lallzyme ex or ex-v with good results. I've heard good things about the Color Pro too. I've just never used it.
Regarding fermentors-Hard to beat Brutes. For $40 or so, you can have a basically indestructible, permanent fermentor that can be used for years. I like the white colored brutes. It is easier to tell when they are perfectly clean. This is a significant detail and I recommend you seek out white ones. Home Depot will order them or amazon can deliver them to you. I use the 28 (sometimes described as 30gallon) gallon ones and a couple of 44 gallon ones. Pro tip-put your brutes on a movers dolly (the Harbor Freight ones work great)-much easier to move around and deal with when full.
What are you going to use for a wine press?